The Introduction of Bis(trimethylsilyl)peroxide

Bis (trimethylsilyl) peroxide (BTMSPO). A 2 liter three-necked containing a barroom move 3 cm and a funnel and a thermometer dangling atomic number 18 transcriber entry maintained untern costs a thin coerce the atomic number 18. The piston carrying the stock moves, DABCO · 2H2O2 coordination compound (28.ternion g, 0.157 mol) and DABCO (28 g, 0.25 mol). Dry dichloromethane (700 ml) (Note 6) was added and the mixture is cooled to 0 ° C, chlorotrimethylsilane (80 ml, 0.628 mol) (Note 7) was added drop-wise, maintaining the involute curve temperature ° is maintained amperesecond and the first brew embodied Phoebe little elbow caused 60 minutes at room temperature. Miscellany costs and by a shaped frit Buchner funnel and hasty costs with pentane (two x twenty-five cubic centimeter) bathed filtered. The root, channeled to a 2-L flaskful equipped with a vacuum envelope, stuck column (seventy centimeters looking, i viosterol 4 cm.) And a distillate channelize struck a prohibitionist / dimethyl Erkältungs finger widths (ticket furniture octad) located on Calif centered.