2016年2月23日星期二
Fe(CO)5 iron pentacarbonyl
Product name: Fe (CO) 5 iron pentacarbonyl
Product Description: Fe (CO) 5, the compounds of Co and Fe, the equation for the chemical reaction: 5CO + Fe → Fe (CO) 5
Physical properties: Under normal atmospheric, it was amber liquid, the density is 1.453 g / cm3 (20.0 ℃). Fe (CO) 5, the melting point is about -20.3 ℃, the point 103.6 ℃, the critical temperature of 286 ℃ boiling. The low temperature to the critical temperature, with the rise in temperature, it is easy to break Fe and Co.
Chemical properties:
1, Fe (CO) 5 is completely dissolved in benzine, benzene, tetrahydronaphthalene, benzaldehyde, acetone, bromination of benzene, benzene and the other solution dichloride.
2, of-15 ℃, steam carbonyl content mixed with the combustion air necessarily create; Less than 34 ℃ temperature, it may be a spontaneous combustion in air.
3, Fe (CO) 5 is very agile and easy to hydrogenated carbonyl content H2Fe (CO) 4 and a metal salt Na2Fe (CO) 4, Fe content halogenating carbonyl (CO) 4I2, and Gerber acyl Fe carbonyl content (CO) 2 form (NO) 2, carbonyl fullerenes [C5H5Fe (CO) 2] and other compounds.
4, Fe (CO) 5 photochemical performance is lively, under the light, Fe (CO) 5 is easy to resolve.
5 depending on the critical temperature of Fe (CO) 5, under normal atmospheric pressure and more than 286 ℃ for thermal decomposition is the most important application of Fe (CO) 5, and is the easiest way industrialization carbonyl .
Application: Pyrolysis micro powder / nano level carbonyl iron, nano iron oxide powder is, magnetic film at the nanometer scale, fiber, nine carbonyl two iron, gasoline, flame retardants, catalysts of anti-explosion agent, CEO of surface film coating, lithography mask iron, antibiotics etc.
Notes: Fe (CO) 5 is tasteless, toxic, flammable, explosive brown liquid, in transportation and storage, we should pay attention to:
1.iron pentacarbonyl be provided in anaerobic jars under sealed metal pressure in air.
2. iron pentacarbonyl should be stored in a cool, well-ventilated place, avoid direct sunlight, away from fire, heat source.
3. gentle with her collision prohibited.
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